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Chapter 1
Atomic Number, Mass, and Isotopes
Key Concepts
This chapter covers how atomic number, mass number, relative atomic mass, and isotopes are used to read periodic table data. You need to distinguish these values accurately in exams.
• Atomic number = number of protons in an atom. It identifies the element.
• In a neutral atom, number of electrons = number of protons.
• Mass number = protons + neutrons in one atom.
• Neutrons = mass number - atomic number.
• Relative atomic mass (Ar) is the weighted average mass of an element’s isotopes.
• Isotopes have the same number of protons but different numbers of neutrons.
• Isotopes have similar chemical properties because they have the same electron arrangement.
• On most periodic tables, the larger decimal value is relative atomic mass, not mass number.
Before you continue: How can you calculate the number of neutrons when atomic number and mass number are given?
Key Terms
• Atomic number - The number of protons in an atom’s nucleus.
• Mass number - The total number of protons and neutrons in one atom.
• Relative atomic mass (Ar) - The weighted mean mass of an element’s isotopes.
• Isotope - An atom of the same element with a different number of neutrons.
• Proton - A positively charged particle in the nucleus.
• Neutron - An uncharged particle in the nucleus.
• Electron - A negatively charged particle outside the nucleus.
Active Recall
Atomic number
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Mass number
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Relative atomic mass (Ar)
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Isotope
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Proton
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Neutron
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Electron
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Worked Examples
1. Finding neutrons
An atom has atomic number 11 and mass number 23.
• Protons = atomic number = 11.
• Neutrons = mass number - atomic number.
• Neutrons = 23 - 11 = 12.
Now you try: An atom has atomic number 17 and mass number 35. Find its neutrons.
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2. Interpreting isotopes
Carbon-12 and carbon-14 are isotopes.
• Carbon’s atomic number is 6, so both atoms have 6 protons.
• Carbon-12 has 12 - 6 = 6 neutrons.
• Carbon-14 has 14 - 6 = 8 neutrons.
• They have the same chemical properties but different masses.
Now you try: Compare chlorine-35 and chlorine-37. State their proton and neutron numbers.
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3. Calculating relative atomic mass
An element has two isotopes: 75% has mass 35, and 25% has mass 37.
• Multiply each isotope mass by its abundance: (35 × 75) + (37 × 25).
• Divide by 100: 3,550 ÷ 100.
• Relative atomic mass = 35.5.
Now you try: An element is 80% isotope 10 and 20% isotope 11. Calculate Ar.
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Practice Questions
• (Easy) Define atomic number.
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• (Easy) An atom has 19 protons and mass number 39. How many neutrons does it have?
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• (Medium) Explain why isotopes of an element have the same chemical properties.
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• (Medium) Chlorine-35 and chlorine-37 are isotopes. State one similarity and one difference.
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• (Hard) Calculate Ar for an element containing 60% isotope 24 and 40% isotope 26.
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• (Hard) An ion has 12 protons and 10 electrons. Identify its charge and explain why.
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Answer Key
• Number of protons.
• 20 neutrons.
• They have the same number and arrangement of electrons.
• Similarity: same number of protons; difference: different numbers of neutrons or different masses.
• Ar = 24.8.
• Charge = 2+; it has lost two electrons.
Exam Tips & Common Mistakes
• Do not confuse atomic number with mass number: atomic number counts protons; mass number counts protons plus neutrons.
• Do not use the decimal relative atomic mass as the neutron calculation. Use the isotope’s whole-number mass number.
• When explaining isotopes, state both parts: same protons, different neutrons.
• Show the weighted-average calculation clearly; markers can award method marks.
• For ion questions, compare protons and electrons. More protons means a positive charge; fewer means a negative charge.
• Use precise phrases such as “same electron arrangement” rather than simply “same structure.”
• In calculations, write the formula before substituting values to make your method easy to follow.
Quick Reference
Key rules
• Atomic number = protons.
• Neutral electrons = protons.
• Neutrons = mass number - atomic number.
• Mass number = protons + neutrons.
• Ar = sum of (isotope
mass × abundance) ÷ total abundance.
• Isotopes: same protons, different neutrons.
• Relative atomic mass is usually a weighted mean, so it may be a decimal.
Mnemonic
PEN:
• P rotons = atomic number
• E lectrons = protons in a neutral atom
• N eutrons = mass number - atomic number
Absolute essentials
• Atomic number identifies the element.
• Mass number counts protons and neutrons in one atom.
• Isotopes are atoms of the same element with different neutron numbers.
• Chemical properties depend mainly on electrons.
• Use isotope abundance when calculating relative atomic mass.
Confidence Check
• I can identify an element from its atomic number. [ ] 1 [ ] 2 [ ] 3 [ ] 4 [ ] 5
• I can calculate neutrons from mass number and atomic number. [ ] 1 [ ] 2 [ ] 3 [ ] 4 [ ] 5
• I can explain what makes atoms isotopes. [ ] 1 [ ] 2 [ ] 3 [ ] 4 [ ] 5
• I can calculate relative atomic mass from isotope abundances. [ ] 1 [ ] 2 [ ] 3 [ ] 4 [ ] 5
• I can distinguish mass number from relative atomic mass. [ ] 1 [ ] 2 [ ] 3 [ ] 4 [ ] 5
End of chapter one. 4 more chapters and about 4,527 words in the full book.
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What's inside: 5 chapters
- 1. Atomic Number, Mass, and Isotopes
- 2. Electron Configuration by Period and Group
- 3. Trends in Atomic Radius and Ion Size
- 4. Ionization Energy and Electronegativity Trends
- 5. Metal, Nonmetal, and Periodic Properties
About this book
"Periodic Table Mastery" is a study guide book by Anonymous with 5 chapters and approximately 4,527 words. Learning the periodic table and element properties.
This book was created using Inkfluence AI, an AI-powered book generation platform that helps authors write, design, and publish complete books. It was made with the Study Guide Generator.
Frequently Asked Questions
What is "Periodic Table Mastery" about?
Learning the periodic table and element properties
How many chapters are in "Periodic Table Mastery"?
The book contains 5 chapters and approximately 4,527 words. Topics covered include Atomic Number, Mass, and Isotopes, Electron Configuration by Period and Group, Trends in Atomic Radius and Ion Size, Ionization Energy and Electronegativity Trends, and more.
Who wrote "Periodic Table Mastery"?
This book was written by Anonymous and created using Inkfluence AI, an AI book generation platform that helps authors write, design, and publish books.
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